Synthesis of new functionalized polyenes by cooligomerization of butadiene with methyl acrylate on nickel catalysts
Identifieur interne : 000222 ( Maroc/Analysis ); précédent : 000221; suivant : 000223Synthesis of new functionalized polyenes by cooligomerization of butadiene with methyl acrylate on nickel catalysts
Auteurs : A. Elamrani [Maroc] ; I. Suisse [France] ; A. Mortreux [France] ; N. Knouzi [Maroc]Source :
- Journal of Molecular Catalysis A: Chemical [ 1381-1169 ] ; 1995.
Abstract
New polyenes are formed in protic media via nickel catalyzed cooligomerization of butadiene with methyl acrylate. High activities are achieved with amino-phosphinite ligands in aprotic solvent. Using a deuterium labeled ligand, the presence of the NH group of the ligand is shown to be the key point for the proton transfer involved in the mechanism.
Url:
DOI: 10.1016/1381-1169(95)00085-2
Affiliations:
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ISTEX:4A745325008BCD53111D9D16FE86D7FDFD8B287DLe document en format XML
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Doukali, Faculté des Sciences, Département Chimie, BP 20, El Jadida</wicri:regionArea><wicri:noRegion>El Jadida</wicri:noRegion></affiliation></author></analytic><monogr></monogr><series><title level="j">Journal of Molecular Catalysis A: Chemical</title><title level="j" type="abbrev">MOLCAA</title><idno type="ISSN">1381-1169</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="1995">1995</date><biblScope unit="volume">101</biblScope><biblScope unit="issue">3</biblScope><biblScope unit="page" from="211">211</biblScope><biblScope unit="page" to="215">215</biblScope></imprint><idno type="ISSN">1381-1169</idno></series><idno type="istex">4A745325008BCD53111D9D16FE86D7FDFD8B287D</idno><idno type="DOI">10.1016/1381-1169(95)00085-2</idno><idno type="PII">1381-1169(95)00085-2</idno></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">1381-1169</idno></seriesStmt></fileDesc><profileDesc><textClass></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">New polyenes are formed in protic media via nickel catalyzed cooligomerization of butadiene with methyl acrylate. High activities are achieved with amino-phosphinite ligands in aprotic solvent. Using a deuterium labeled ligand, the presence of the NH group of the ligand is shown to be the key point for the proton transfer involved in the mechanism.</div></front></TEI><affiliations><list><country><li>France</li><li>Maroc</li></country><region><li>Hauts-de-France</li><li>Nord-Pas-de-Calais</li></region><settlement><li>Villeneuve d'Ascq</li></settlement></list><tree><country name="Maroc"><noRegion><name sortKey="Elamrani, A" sort="Elamrani, A" uniqKey="Elamrani A" first="A." last="Elamrani">A. Elamrani</name></noRegion><name sortKey="Knouzi, N" sort="Knouzi, N" uniqKey="Knouzi N" first="N." last="Knouzi">N. Knouzi</name></country><country name="France"><region name="Hauts-de-France"><name sortKey="Suisse, I" sort="Suisse, I" uniqKey="Suisse I" first="I." last="Suisse">I. Suisse</name></region><name sortKey="Mortreux, A" sort="Mortreux, A" uniqKey="Mortreux A" first="A." last="Mortreux">A. 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